Which of the following are aromatic species?
$(A)$ Cyclohexa$-2,4-$dienyl cation
$(B)$ Naphthalene
$(C)$ Tropone (Cycloheptatrienone)
$(D)$ Cyclohexa$-1,3-$diene

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(B) To determine aromaticity,a species must follow $H$ückel's rule ($4n+2$ $\pi$ electrons),be planar,and have a fully conjugated system.
$(A)$ Cyclohexa$-2,4-$dienyl cation: This species has $4$ $\pi$ electrons. It is not fully conjugated because of the $sp^3$ carbon atom. It is non-aromatic.
$(B)$ Naphthalene: This is a polycyclic aromatic hydrocarbon with $10$ $\pi$ electrons ($n=2$ in $4n+2$). It is planar and fully conjugated. It is aromatic.
$(C)$ Tropone: The oxygen atom is more electronegative than carbon,pulling electron density towards itself,which creates a resonance structure with a tropylium cation ($7$ carbons,$6$ $\pi$ electrons). This makes it aromatic.
$(D)$ Cyclohexa$-1,3-$diene: This has $4$ $\pi$ electrons and is not fully conjugated due to $sp^3$ carbons. It is non-aromatic.
Therefore,only $B$ and $C$ are aromatic species.

Explore More

Similar Questions

$TNT$ has the structure

Which of the following products is formed when $n-$heptane is passed over $(Al_2O_3 + Cr_2O_3)$ catalyst at $773\ K$?

The correct order of the rate of $EAS$ (electrophilic aromatic substitution) for the following compounds is:

In the mixture of conc. $H_2SO_4$ and $HNO_3$,the nitrating species is:

Answer the following questions: Which product is obtained when benzene is heated with $CH_3Cl$ in the presence of $AlCl_3$? Why?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo